Dry Test Analysis for action of KMnO4 Solution
Boil 1 gm of mixture with 2 cm3 of dilute H2SO4 to eliminate all gases. Then cool it and add KMnO4 Solution dropwise.
Sr. No. |
Observations |
Interference |
1. |
Colour of KMnO4 solution with the formation of characteristic
product: a. Colorless and odourless gas, turns lime water milky-CO2. b. Colour of reaction mixture becomes orange or brown. Cool, and water
and SO2. On shaking, CS2 layer acquires a colour: i.
Violet ii. Orange iii.
Smell of Cl2.
Dip a litmus paper, it is decolorized. |
Oxalate or Tartrate (or both). Iodide Bromide Chloride |
2. |
Colour of KMnO4 solution is decolorized without the
formation of any characteristic product. |
All above mentioned radicals are absent. Fe2+ & Sn2+ may be present. |
3. |
Colour of KMnO4 solution is not decolorized. |
All above mentioned radicals are absent. |
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