Dry Test Analysis for action of KMnO4 Solution

 

Boil 1 gm of mixture with 2 cm3 of dilute H2SO4 to eliminate all gases. Then cool it and add KMnO4 Solution dropwise.

Sr. No.

Observations

Interference

1.

Colour of KMnO4 solution with the formation of characteristic product:

a.      Colorless and odourless gas, turns lime water milky-CO2.

b.      Colour of reaction mixture becomes orange or brown. Cool, and water and SO2. On shaking, CS2 layer acquires a colour:

i.                 Violet


ii.                Orange


iii.               Smell of Cl2. Dip a litmus paper, it is decolorized.

 

 

Oxalate or Tartrate (or both).

 

 

Iodide

Bromide

Chloride

 

 

2.

Colour of KMnO4 solution is decolorized without the formation of any characteristic product.

All above mentioned radicals are absent.

Fe2+ & Sn2+ may be present.

3.

Colour of KMnO4 solution is not decolorized.

All above mentioned radicals are absent.

 


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